Crystal Structure of N-Allyl-4-Methylbenzenesulfonamide
crystal structure, aryl sulfonamide, hydrogen bond, offset pi–pi interactions
The title compound, C10H13NO2S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluenesulfonyl chloride. The sulfonate S— O bond lengths are 1.4282 (17) and 1.4353 (17) A˚ , and the C—N—S—C torsion angle involving the sulfonamide moiety is 61.0 (2). In the crystal, centrosymmetric dimers of the title compound are present via intermolecular N—H...O hydrogen bonds between sulfonamide groups. These dimers are linked into ribbons along the c-axis direction through offset pi–pi interactions.
Patel, Z. S., Stevens, A. C., Bookout, E. C., Staples, R. J., Biros, S. M., & Ngassa, F. N. (2018). Crystal structure of N -allyl-4-methylbenzenesulfonamide. Acta Crystallographica Section E Crystallographic Communications, 74(8), 1126–1129. https://doi.org/10.1107/S2056989018010290
Patel, Zeel S.; Stevens, Amanda C.; Bookout, Erin C.; Staples, Richard J.; Biros, Shannon M.; and Ngassa, Felix N., "Crystal Structure of N-Allyl-4-Methylbenzenesulfonamide" (2018). Funded Articles. 108.