Keywords
crystal structure, sulfonamide, intermolecular N—H⋯O hydrogen bonding, intermolecular C—H⋯O hydrogen bonding.
Disciplines
Chemistry
Abstract
The crystal structure of the title sulfonamide, C10H15NO2S, comprises two molecules in the asymmetric unit. The S=O bond lengths of the sulfonamide functional group range from 1.428 (2) to 1.441 (2) Å, with S—C bond lengths of 1.766 (3) Å (for both molecules in the asymmetric unit), and S—N bond lengths of 1.618 (2) and 1.622 (3) Å, respectively. When both molecules are viewed down the N—S bond, the propyl group is gauche to the toluene moiety. In the crystal structure, molecules of the title compound are arranged in an intricate three-dimensional network that is formed via intermolecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure was refined from a crystal twinned by inversion.
Original Citation
Stenfors, B. A., Collins, R. C., Duran, J. R. J., Staples, R. J., Biros, S. M., & Ngassa, F. N. (2020). Crystal structure of 4-methyl-N-propylbenzenesulfonamide. Acta Crystallographica Section E: Crystallographic Communications, 76(7), 1070–1074. https://doi.org/10.1107/S2056989020007756
ScholarWorks Citation
Stenfors, Brock A.; Collins, Rachel C.; Duran, Jonah R.J.; Biros, Shannon; and ngassa, felix, "Crystal structure of 4-methyl-N-propylbenzenesulfonamide" (2020). Open Access Publishing Support Funded Articles. 152.
https://scholarworks.gvsu.edu/oapsf_articles/152
