Formation of Phosphorus (III) Nitrogen Bonds

Presentation Type

Poster/Portfolio

Presenter Major(s)

Chemistry

Mentor Information

John Bender

Department

Chemistry

Location

Kirkhof Center KC28

Start Date

11-4-2012 9:00 AM

Keywords

Physical Science

Abstract

The formation of P(III)N bonds is made difficult by the ease of which the P(III) is oxidized to P(V). A suitable N nucleophile must be chosen so that oxidation of the P atom is avoided. Lithium Nitride was chosen as the nucleophile as the N is in its most reduced form. In this study, lithium nitride was reacted with phosphine chlorides with a variety of R groups to asses their reactivity towards the lithium nitride.

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Apr 11th, 9:00 AM

Formation of Phosphorus (III) Nitrogen Bonds

Kirkhof Center KC28

The formation of P(III)N bonds is made difficult by the ease of which the P(III) is oxidized to P(V). A suitable N nucleophile must be chosen so that oxidation of the P atom is avoided. Lithium Nitride was chosen as the nucleophile as the N is in its most reduced form. In this study, lithium nitride was reacted with phosphine chlorides with a variety of R groups to asses their reactivity towards the lithium nitride.