Investigation of Phosphorus (III) Nitrogen Compounds

Presentation Type

Poster/Portfolio

Presenter Major(s)

Chemistry

Mentor Information

John Bender, benderj@gvsu.edu

Department

Chemistry

Location

Henry Hall Atrium 34

Start Date

13-4-2011 10:00 AM

End Date

13-4-2011 11:00 AM

Keywords

Physical Science

Abstract

Macroscale synthesis of phosphorous (III) nitride is a process still in development. There is little known about bulk phosphorous (III) nitride, but it is expected to be applicable for use in electronic materials. Synthesis of this product was attempted using lithium nitride and several electrophilic phosphorous sources with formula PX3. Reactions using PCl3 have resulted in the formation of an insoluble orange solid. Reactions using (CH3O)3P and [(CH3)2N]3P have produced insoluble off-white solids. Several reactions using akyl and aryl phosphorous dichlorides have also been performed and produce slightly soluble polymeric compounds. These results have been characterized using infrared and NMR spectroscopy.

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Apr 13th, 10:00 AM Apr 13th, 11:00 AM

Investigation of Phosphorus (III) Nitrogen Compounds

Henry Hall Atrium 34

Macroscale synthesis of phosphorous (III) nitride is a process still in development. There is little known about bulk phosphorous (III) nitride, but it is expected to be applicable for use in electronic materials. Synthesis of this product was attempted using lithium nitride and several electrophilic phosphorous sources with formula PX3. Reactions using PCl3 have resulted in the formation of an insoluble orange solid. Reactions using (CH3O)3P and [(CH3)2N]3P have produced insoluble off-white solids. Several reactions using akyl and aryl phosphorous dichlorides have also been performed and produce slightly soluble polymeric compounds. These results have been characterized using infrared and NMR spectroscopy.