Coordination Exploration, f-element Complexation, Extraction and Synthesis of Novel Multidentate Carbamoylmethylphosphine-Oxide Ligands: With Nuclear Waste Remediation Implications

Presentation Type

Poster/Portfolio

Presenter Major(s)

Chemistry

Mentor Information

Shannon Biros, Christopher Lawrence

Department

Chemistry

Location

Henry Hall Atrium 60

Start Date

10-4-2013 9:00 AM

End Date

10-4-2013 10:00 AM

Keywords

Environment, Physical Science

Abstract

Carbamoylmethylphosphine oxide (CMPO) ligands have been used in industry to complex lanthanides and actinides primarily for the TRUEX nuclear waste remediation process. The anticipated goal is to improve upon current nuclear waste remediation strategies using novel tripodal CMPOs. The research presented in this poster will include the synthesis of multidentate CMPOs, their complexes with and extraction of f-elements. Also included is the utilization of CMPOs to computationally explore fundamental f-element coordination chemistry.

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Apr 10th, 9:00 AM Apr 10th, 10:00 AM

Coordination Exploration, f-element Complexation, Extraction and Synthesis of Novel Multidentate Carbamoylmethylphosphine-Oxide Ligands: With Nuclear Waste Remediation Implications

Henry Hall Atrium 60

Carbamoylmethylphosphine oxide (CMPO) ligands have been used in industry to complex lanthanides and actinides primarily for the TRUEX nuclear waste remediation process. The anticipated goal is to improve upon current nuclear waste remediation strategies using novel tripodal CMPOs. The research presented in this poster will include the synthesis of multidentate CMPOs, their complexes with and extraction of f-elements. Also included is the utilization of CMPOs to computationally explore fundamental f-element coordination chemistry.