Coordination Exploration, f-element Complexation, Extraction and Synthesis of Novel Multidentate Carbamoylmethylphosphine-Oxide Ligands: With Nuclear Waste Remediation Implications
Presentation Type
Poster/Portfolio
Presenter Major(s)
Chemistry
Mentor Information
Shannon Biros, Christopher Lawrence
Department
Chemistry
Location
Henry Hall Atrium 60
Start Date
10-4-2013 9:00 AM
End Date
10-4-2013 10:00 AM
Keywords
Environment, Physical Science
Abstract
Carbamoylmethylphosphine oxide (CMPO) ligands have been used in industry to complex lanthanides and actinides primarily for the TRUEX nuclear waste remediation process. The anticipated goal is to improve upon current nuclear waste remediation strategies using novel tripodal CMPOs. The research presented in this poster will include the synthesis of multidentate CMPOs, their complexes with and extraction of f-elements. Also included is the utilization of CMPOs to computationally explore fundamental f-element coordination chemistry.
Coordination Exploration, f-element Complexation, Extraction and Synthesis of Novel Multidentate Carbamoylmethylphosphine-Oxide Ligands: With Nuclear Waste Remediation Implications
Henry Hall Atrium 60
Carbamoylmethylphosphine oxide (CMPO) ligands have been used in industry to complex lanthanides and actinides primarily for the TRUEX nuclear waste remediation process. The anticipated goal is to improve upon current nuclear waste remediation strategies using novel tripodal CMPOs. The research presented in this poster will include the synthesis of multidentate CMPOs, their complexes with and extraction of f-elements. Also included is the utilization of CMPOs to computationally explore fundamental f-element coordination chemistry.